ELECTROCATALYSIS BY NANOPARTICLES: OXIDATION OF FORMIC ACID AT MANGANESE OXIDE NANORODS-MODIFIED PT PLANAR AND NANOHOLE-ARRAYS
Tìm thấy 10,000 tài liệu liên quan tới tiêu đề "Electrocatalysis by nanoparticles: Oxidation of formic acid at manganese oxide nanorods-modified Pt...":
The electro-oxidation of formic acid (an essential reaction in direct formic acid fuel cells) is a challenging process because of the deactivation of anodes by the adsorption of the poisoning intermediate carbon monoxide (CO). Pt electrodes in two geometries (planar and nanohole-array) were modified[r]
Figure 4a shows linear sweep voltammetry of the TiO 1.988 N 0.012 photoanode before and after cobalt treatment. After the cobalt treatment, the photocurrent density at 1.23 V RHE increases from 0.23 mA/cm 2 (without cobalt) to 0.61 mA/cm 2 (60% higher than the unmodified TiO 2 s[r]
Table 4 is obtained and the failured components which can be detected in the GT are identified. 5. Diagnosticability improvement in the GT The subsystem G 0 given at the top of the matrix in Fig. 5 describes the process without redundant data and and the u[r]
2 d ·sin θ = λ Where d is the lattice spacing, λ is the wavelength of , 1.5406 Å. The c -axis lattice constants for these samples can be calculated, and Figure 3.7 shows the To study the structure and crystallinity of hydrothermally grown Zn 1-x Mn x O nanorods[r]
water been considered. 2 Their presence at low levels presents analytical challenges, and the environmental impact and public health effects of long-term, low-level expo- sure and combinatory effects of these compounds requires further study. Particular co[r]
Nanocomposites of graphene oxide (GO) and tungsten oxide (WO3) nanobricks were synthesized by co-dispersing graphene oxide and tungsten oxide nanobricks in bi-distilled water with different weight ratios (0.1, 0.3 and 0.5 wt.% of graphene oxide). The ammonia gas sensing properties of nanocomposites[r]
Blades and vanes for gas turbines, usually made of Ni-based superalloys, are exposed at very high temperature in severe oxidation and corrosion environments. Nowadays, thermal barrier coating systems (TBCs) have been applied to protect them against such severe working conditions. In this study, Pt a[r]
2.4.3 Immobilization of urease over the polymer membrane for urea biosensor: Solid state biosensors are adopted more as compared to liquid state as the stability of the enzyme is very less in the liquid state. The immobilization of the biological component should be at[r]
μ M - 5.7 mM with a sensitivity of 88 µA/cm 2 .mM. The sensor had a good reproducibility and remained stable over 30 days. A wide variety of matrices, including inorganic materials, organic polymers, and other commercially available solid supports, have been used for[r]
The current study proposes a novel binary catalyst system (composed of metal/metal oxide nanoparticles) as a promising electrocatalyst in formic acid oxidation. The electro-catalytic oxidation of formic acid is carried out with binary catalysts of Pt nanoparticles (nano-Pt) and manganese oxide nanor[r]
The last part of the thesis explores the use of SPIONs for bladder cancer therapy. Non-specific uptake by macrophages is not a problem for bladder cancers, and folate receptors are also not over-expressed. However, the short residence time of drug carriers in t[r]
4.3 The use of nanorods for applied electric field Prominent among them is in the use in display technologies. By changing the orientation of the nanorods with respect to an applied electric field, the reflectivity of the rods can be altered, resulting[r]
Results and Discussion Effect of Thiocarbamide on Morphology of ZnO Nanorods Figure 1 illustrates the SEM images of ZnO nanorods deposited onto SnO 2 covered glass substrates by the spray pyrolysis process using zinc chloride (Fig. 1 a) and[r]
Received: 26 August 2008 / Accepted: 3 October 2008 / Published online: 23 October 2008 Ó to the authors 2008 Abstract A new method for preparing magnetic iron oxide nanoparticles coated by organic dye-doped silica shell was developed in this article. Iron oxide na[r]
Squilla (Oratosquilla nepa) was minced and divided into 3 lots. Each lot was treated with 3 different acids such as formic acid, hydrochloric acid and sulphuric acid, the pH was brought down to 3.5, 2.5 and 2.5 of the respective lot. Liquefaction of tissue was more pronounced in the first few days.[r]
Sharma, Green synthesis of multifunctional zinc oxide (ZnO) nanoparticles using Cassia fistula plant extract and their photodegradative, antioxidant and antibacterial activities, Mater. N[r]
Fakhri, Study of the adsorption of methyl orange from aqueous solution using nickel oxide nanoparticles: equilibrium and kinetics studies, J. Chang, Adsorption kinetics and isotherms for[r]
The morphologies of the as-prepared products are demonstrated in Figs. 2 a and b. The products show obvious rod-like shape up to 2000 nm in length and 20–30 nm in diameter. Shown in Fig. 2 b is a typical TEM image, in which the nanorods were covered by a thin film <[r]
Fig. 2 Schematic diagram of the experimental setup Removal of iron and manganese The method we select to remove manganese was potassium permanganate (KMnO 4 ) oxidation. Characteristics of oxidation with KMnO 4 are followed Eq. 1 and[r]
Abstract Exploiting electrocatalysts with high activity for glucose oxidation is of central importance for practical applications such as glucose fuel cell. Pt-decorated nanoporous gold (NPG-Pt), created by depositing a thin layer of Pt on NPG surfa[r]